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Study on the equilibrium in the MBr 2 CH 3 OHH 2 O System (M = Sr 2+ , Ba 2+ ) at 25° C
Author(s) -
Zlateva I.,
Stoev M.
Publication year - 1985
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.19855250623
Subject(s) - dehydration , crystallization , solubility , solvation , chemistry , component (thermodynamics) , crystal (programming language) , crystallography , analytical chemistry (journal) , thermodynamics , chromatography , ion , physics , organic chemistry , biochemistry , computer science , programming language
The dehydration processes in the three‐component system MBr 2 CH 3 OHH 2 O (M = Sr 2+ , Ba 2+ ) have been studied at 25°C by physico‐chemical analyses. Crystallization fields for the lower crystal hydrates SrBr 2 · H 2 O and BaBr 2 · H 2 O have been found. The solubility curves exhibit complex‐formation processes. The dehydration and solvation processes in three‐component system such as MBr 2 CH 3 OHH 2 O at 25°C with M = Mg 2+ , Ca 2+ , Sr 2+ , Ba 2+ have been discussed in general terms.