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Premium Synthesis and spectroscopic study of complexes of antimony pentachloride with some benzonitrile derivatives
Author(s)
AlvarezValdes A.,
GomezVaamonde C.,
Masaguer J. R.,
GarciaVazquez J. A.
Publication year1985
Publication title
zeitschrift für anorganische und allgemeine chemie
Resource typeJournals
PublisherWILEY‐VCH Verlag
Abstract The complexes SbCl 5 · L (L = 2,3 and 4‐chlorobenzonitriles and 2,3 and 4‐aminobenzonitriles) have been isolated and investigated by conductivity and IR and Raman spectral measurement. From the IR spectra it is inferred that in all complexes, coordination of the ligands to the Sb takes place through the nitrogen atom of the nitrile group. In addition, the spectral data are in full accord with a molecular adduct of local C 4v symmetry for the SbCl 5 N moiety.
Subject(s)adduct , antimonate , antimony , benzonitrile , chemistry , group (periodic table) , infrared spectroscopy , inorganic chemistry , medicinal chemistry , moiety , nitrile , nitrogen , nitrogen atom , optics , organic chemistry , physics , polymer chemistry , raman spectroscopy , stereochemistry
Language(s)English
SCImago Journal Rank0.354
H-Index66
eISSN1521-3749
pISSN0044-2313
DOI10.1002/zaac.19855230428

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