Premium
Studies on Systems of Salts and Mixed Solvents. XXXI. On the Solubility and Solvation Behaviour of Magnesium Chloride in Mixed Aqueous Organic Solvents
Author(s) -
Emons H.H.,
Pollmer K.
Publication year - 1985
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.19855210226
Subject(s) - solubility , solvation , chemistry , magnesium , aqueous solution , inorganic chemistry , chloride , electrolyte , solvent , organic chemistry , electrode
Continuing our investigations on the solvation of chlorides of selected main group elements in concentrated solutions of electrolytes this paper is intended to discuss the possibility of the qualitative interpretation of the solubility data by the example of regions of the 25°C solubility isotherm of 11 systems of the type MgCl 2 H 2 O — Organic solvent. As to magnesium chloride a significant influence on the solubility can be noticed in a general analogy to aluminium(III)‐chloride according to the solvent groups of the Kolthoff classification. The results obtained correlate with the results of spectroscopic investigations. Special significance is attached to solid phases so far unknown in literature.