Crystal structure of zinc‐tetrametaphosphate octahydrate: Zn 2 P 4 O 12  · 8 H 2 O | Zendy

AverbuchPouchot M. T. | Zendy

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Crystal structure of zinc‐tetrametaphosphate octahydrate: Zn 2 P 4 O 12 · 8 H 2 O

Author(s) -

AverbuchPouchot M. T.

Publication year - 1983

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.19835030825

Subject(s) - triclinic crystal system , zinc , crystallography , crystal structure , chemistry , hydrogen bond , salt (chemistry) , crystal (programming language) , molecule , inorganic chemistry , organic chemistry , computer science , programming language

Crystal structure of zinc tetrametaphosphate octahydrate: Zn 2 P 4 O 12 · 8 H 2 O has been solved using 1888 X‐ray reflections with a final R value: 0.031. This salt is triclinic, P 1 , with Z = 1 and the following unit cell dimensions: a = 8.610(5), b = 7.137(5), c = 7.108(5) Å, α = 96.09(5), β = 105.99(5), γ = 100.49(5)°. This salt is the third example of an hydrated tetrametaphosphate of a bivalent cation. The two zinc atoms are octahedrally coordinated. A complete hydrogen bond scheme is given.

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