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Structure of Diacetato bis (2,4,6 Trimethyl Pyridine) Copper(II)
Author(s) -
Busnot Annie,
Busnot Florent,
Leclaire André,
Bernard Maurice
Publication year - 1983
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.19835030822
Subject(s) - copper , monoclinic crystal system , pyridine , molecule , crystallography , chemistry , atom (system on chip) , crystal structure , medicinal chemistry , organic chemistry , computer science , embedded system
(2.4.6 trimethyl pyridine) 2 Cu(CH 3 COO) 2 has been obtained as violet needles by slow evaporation. The crystals belong to the monoclinic system, space group P2 1/C with two molecules in a unit cell of dimension:a = 7.842 (1), b = 16.384 (2), c = 8.320 (2) Å, β = 101.91 (1)°. The structure was solved by heavy atom method and refined by a least squares method (R = 0.029). The coordination of copper is 4 + 2. The atom arrangements of this structure is very near to the copper acetate one solvated by one water molecule and two 3.4 dimethyl pyridine molecules.