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Nitrosyl Rhenium Complexes Syntheses, Properties, and Structures of Oxalato Derivatives
Author(s) -
Mitra T.,
Bhadra A.,
Sen S.,
Sen B. K.,
Bandyopadhyay P.
Publication year - 1983
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.19835020731
Subject(s) - rhenium , oxalic acid , chemistry , conductance , aqueous solution , aqueous medium , medicinal chemistry , spectral properties , elemental analysis , inorganic chemistry , organic chemistry , computational chemistry , combinatorics , mathematics
The free acid, H[Re(NO)(C 2 O 4 )(OH) 2 (H 2 O)] has been prepared from the reaction of Re(NO)(OH) 3 H 2 O with oxalic acid in aqueous medium. The K + , NH 4 + and Pb 2+ salts of the acid have been isolated. Nonelectrolytic diimino derivatives, Re(NO)(C 2 O 4 )X · L (X = 1, 10‐phenanthroline, 2,2′‐dipyridyl; L OH − , Cl − ) have been synthesized. The complexes have been characterised through elemental analyses, spectral (u.v., vis., i.r.) properties, magnetic and conductance data and their structures are proposed.