Premium
Synthesis and complex formation of stereoisomers of 1,3‐Diphenyl‐2‐thioxo‐4,5‐bis(hydroxyimino)‐Imidazoline
Author(s) -
Serin S.,
Bekaroǧlu Ö.
Publication year - 1983
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.19834960121
Subject(s) - imidazoline receptor , chemistry , stereochemistry , medicinal chemistry , medicine
The new α‐dioxime, 1,3‐diphenyl‐2‐thioxo‐4,5‐bis‐(hydroxyimino)‐imidazoline, DTIH 2 , has been synthesized. Anti ‐ and amphi ‐forms of DTIH 2 could be separated. The anti ‐ and amphi ‐forms of Cu II , Ni II , Co II , and Co III complexes have been isolated and their structures identified by using IR, UV‐Visible and elemental analyses. The interconversion of anti ‐ and amphi ‐Ni II complexes has been studied.