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Normal Coordinate Analysis of the Radicals CF 3 O 2 and C 2 F 5
Author(s) -
Snelson A.,
Cyvin B. N.,
Cyvin S. J.
Publication year - 1981
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.19814821115
Subject(s) - radical , force constant , chemistry , analytical chemistry (journal) , physics , atomic physics , nuclear magnetic resonance , molecule , organic chemistry , chromatography
Normal coordinate analyses are performed for the radicals CF 3 O 2 and C 2 F 5 . The force constants are given. The analysis of CF 3 O 2 includes four isotopic compounds with 16 O and 18 O. The calculated vibrational frequencies are in good agreement with previously published observed data. A few changes are proposed in the previous tentative assignments of fundamentals and approximate mode descriptions.