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Synthesis and characterization of some Alkoxide Derivatives of Copper(II)
Author(s) -
Singh J. V.,
Baranwal B. P.,
Mehrotra R. C.
Publication year - 1981
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.19814770633
Subject(s) - anhydrous , copper , alkoxide , chemistry , lithium (medication) , alkyl , inorganic chemistry , chloride , organic chemistry , polymer chemistry , catalysis , medicine , endocrinology
A number of alkoxides of copper(II), Cu(OR) 2 (where R is a primary, secondary or tertiary alkyl group) have been synthesised by the reactions of anhydrous copper(II) chloride with lithium alkoxides in 1:2 molar and also by alcoholysis and trans‐esterification techniques. All the derivatives have been characterized on the basis of various physico‐chemical studies, viz., infra‐red, electronic reflectance spectra and magnetic susceptibility measurements.