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Crystal structure of [Zn(NH 3 + CH 2 (CH 3 )P(O)O − )Cl 2 ] (α‐aminomethyl(methyl)phosphinic)zinc(II) dichloride
Author(s) -
Žák Z.,
Kožíšek J.,
Głowiak T.
Publication year - 1981
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.19814770630
Subject(s) - monoclinic crystal system , diffractometer , zinc , chemistry , crystallography , crystal structure , molecule , ligand (biochemistry) , group (periodic table) , stereochemistry , organic chemistry , biochemistry , receptor
Abstract The title compound is monoclinic, space group P2 1 /c, Z = 4, with a = 6.632, b = 11.890, c = 10.012 Å and β 90.80°. The structure, which was solved by direct methods and refined to R = 0.086 for 1783 diffractometer intensities, consists of infinite (POZnOP) chaines. Zn atoms are coordinated tetrahedrally by 2 Cl and 2 O atoms of different ligand molecules with ZnO and ZnCl distances of 1.95 and 2.24 Å, respectively.