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Novel chelated compounds of Bis‐β‐carbomethoxyethltin(IV)
Author(s) -
Garad M. V.,
Gopinathan Sarada,
Gopinathan C.
Publication year - 1980
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.19804650124
Subject(s) - dibenzoylmethane , benzophenone , acetylacetone , chelation , chemistry , quinoline , halogenation , ligand (biochemistry) , medicinal chemistry , polymer chemistry , organic chemistry , receptor , biochemistry
Bi‐ and tri‐denate Chelating ligands (acetylacetone, salicylasehyde, 8‐hydroxy quinoline, dibenzoylmethane, benzoyl phenhydroxlmanine, 2‐hydroxy benzophenone, 2‐hydroxy 4‐methoxy benzophenone and salichyaldine) replace cholrine atoms of bis‐β‐carbomethoxyethyl dischlorotin (IV) to form new stable Cheleted compounds. Bromination studies under mild conditions indicate that in these compounds the Cheleated ligand part is preferentially cleaved. The new compounds are characterized by elemental analysis. IR and PMR spectra and molecular weight, and possible structures have been assigned.