Structural relations between some Chromium(III) and Molybdenum(III) Coordination Compounds with 4‐methylpyridine | Zendy

Brenčič J. V. | Zendy; Leban I. | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Structural relations between some Chromium(III) and Molybdenum(III) Coordination Compounds with 4‐methylpyridine

Author(s) -

Brenčič J. V.,

Leban I.

Publication year - 1980

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.19804650119

Subject(s) - triclinic crystal system , isostructural , molybdenum , chromium , crystallography , group (periodic table) , chemistry , stereochemistry , crystal structure , unit (ring theory) , inorganic chemistry , mathematics , organic chemistry , mathematics education

MCl 3 Pic 3 (Pic = 4‐methylpyridine, M = Cr, Mo) both crystalize in the triclinic space group with close unit cell dimensions. MCl 3 Pic 3 1/2Pic pair is isostructural as well. MoCl 3 Pic 3 1/2Pic has P2 1/n space group with the following cell dimensions: a = 8.595(6), b = 17.472(17), c = 15.911(19) Å and β = 95.80(6)°. Ligands around Mo are in the trans configuration. Average MoCl and MoN distances are 2.41(1) and 2.20(1) Å.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research