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Base Hydrolysis of Reinecke's Salt. Mechanism of the alkali dependent reaction path
Author(s) -
Kita P.,
Swinarski A.
Publication year - 1980
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.19804640118
Subject(s) - alkali metal , chemistry , hydrolysis , salt (chemistry) , reaction mechanism , path (computing) , base (topology) , reaction rate constant , reaction rate , mechanism (biology) , ion , inorganic chemistry , thermodynamics , computational chemistry , kinetics , organic chemistry , catalysis , physics , mathematics , mathematical analysis , quantum mechanics , computer science , programming language
The influence of NCS − ion concentration on the rate of base hydrolysis of trans‐[Cr(NK 3 ) 2 (NCS) 4 ] − complex has been examined. The form of the pseudo‐first‐order rate constants dependence on [NCS − ] is used as a criterion of the reaction mechanism. The mass‐law (rate) retardation effect in the rate determining reaction stage suggests the D CB mechanism for the alkali dependent path.