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Metal Complexes of Poly(Triallyl Phosphate)
Author(s) -
de Bolster M. W. G.,
de Jong G.,
Smit C. N.,
Snoeks J. M.
Publication year - 1980
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.19804630126
Subject(s) - chemistry , monomer , polymerization , metal , polymer , acetone , solvent , salt (chemistry) , coordination sphere , metal ions in aqueous solution , stoichiometry , phosphate , inorganic chemistry , coordination polymer , polymer chemistry , nuclear chemistry , organic chemistry
Polymerization of triallyl phosphate results in an insoluble polymer that is capable of coordination to metal ions. The solid products obtained when the polymer was reacted with metal salts in water, ethanol and acetone were studied with the aid of spectroscopic techniques. The stoichiometry of the products depends on the concentration of the metal salt and the nature of the solvent used in the preparation. The final products can be described as species M(p ‐ TAP) m (anion) n , M = Mg, Mn, Co, Ni, Cu, Zn, Cd(II), Fe(III); p ‐ TAP = one unit of the polymer; anion = ClO 4 − , BF 4 − , NO 3 − Cl − , I − , NCS − ; n = 2,3; m = 2‐4. The composition and structure(the first coordination sphere) of the final products are similar to those found for monomeric phosphoryl ligands.