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Thionitrosyl Complexes of Ruthenium and Osmium
Author(s) -
Pandey K. K.,
Agarwala U. C.
Publication year - 1980
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.19804610135
Subject(s) - osmium , triphenylarsine , ruthenium , triphenylphosphine , chemistry , hydrate , organic chemistry , catalysis
The ruthenium trichloride hydrate and osmium tricholide react with (NSCl) 3 in presence of triphenylphosphine and triphenylarsine to give thionitrosyl complexes M(NS)Cl 3 L 2 (M) Rn, or Os; L PPh 3 or AsPh 3 .
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