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1‐Substituted 1‐(2‐Aminoethoxy)‐1‐sila‐2,8‐dioxa‐5‐azacyclooctanes ‐ proposed name: Pseudosilatranes
Author(s) -
Piekos R.,
Sujecki R.,
Sankowski M.
Publication year - 1979
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.19794540127
Subject(s) - diethanolamine , benzene , chemistry , medicinal chemistry , stereochemistry , organic chemistry
By reacting equimolar quantities of R(R′O) 2 SiOCH 2 CH 2 NR 2 ″ (R = CH 3 , C 6 H 5 , CH 3 O, C 2 H 5 O; R′ = CH 3 , C 2 H 5 ; R″ = H, CH 3 ) and Diethanolamine, appropriate 1‐substituted 1‐(2‐aminoethoxy)‐1‐sila‐2,8‐dioxa‐5‐azacyclooctanes, RSi[(OCH 2 CH 2 ) 2 NR′](OCH 2 CH 2 NR 2 ″) have been obtained for which the name “pseudosilatranes” has been proposed. The compounds are strongly associated in dilute benzene solutions.