Premium
Imido Derivatives of Titanium (IV)
Author(s) -
Nahar K. R.,
Solanki A. K.,
Bhandari A. M.
Publication year - 1979
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.19794490121
Subject(s) - anhydrous , stoichiometry , titanium , benzene , chemistry , acetamide , medicinal chemistry , melting point , benzamide , nicotinamide , inorganic chemistry , polymer chemistry , organic chemistry , nuclear chemistry , enzyme
Reactions of titanium(IV) isopropoxide with acetamide, benzamide, and nicotinamide in different stoichiometric ratios in anhydrous benzene yielded imido derivatives of type (Pr i O) 4‐n Ti(NHOCR) n where n = 1, 2, 3, and 4; R = CH 3 , C 6 H 5 , and C 5 H 4 N. All these complexes are insoluble in common organic solvents suggesting their polymeric nature. All these derivatives, with the exception of three which have characteristic melting points, did not sublime at 250°C in vacuo nor did they appear to decompose appreciably below 300°C. I.R. spectra of these derivatives are discussed.