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Nitric Oxide Complexes of Molybdenum. Part I
Author(s) -
Bhattacharyya S.,
Bandyopadhyay N. N.,
Rakshit S.,
Bandyopadhyay P.
Publication year - 1979
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.19794490120
Subject(s) - molybdenum , aqueous solution , chemistry , titration , conductance , inorganic chemistry , molybdenum oxide , oxide , nitrosylation , nitric oxide , organic chemistry , physics , condensed matter physics
A new method of synthesis of nitrosyl‐molybdenum complexes involving nitrosylation of molybdenum in aqueous acidic medium is described. The isolated compounds are of the types Mo(NO) 2 Cl 2 (H 2 O) 2 , [Mo(NO) 2 Cl] 2− , Mo(NO) 2 Cl 2 X 2 (X = dipy, phen) and [Mo(NO) 2 (OH) 4 ] 2− . They are stable in aqueous solution. Their properties have been described have been described using u.v.‐visible and i.r. spectra, magnetic moment, conductance measurements and pH titrations.
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