Interaction of MnO 3 F with HF and HCl: Matrix‐isolation infrared spectral studies. The vibrational spectrum of MnO 3 Cl | Zendy

Varetti E. L. | Zendy; Müller A. | Zendy

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Interaction of MnO 3 F with HF and HCl: Matrix‐isolation infrared spectral studies. The vibrational spectrum of MnO 3 Cl

Author(s) -

Varetti E. L.,

Müller A.

Publication year - 1978

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.19784420131

Subject(s) - matrix isolation , infrared spectroscopy , infrared , matrix (chemical analysis) , chemistry , spectral line , spectroscopy , analytical chemistry (journal) , materials science , physics , organic chemistry , optics , chromatography , quantum mechanics , astronomy

The interaction MnO 3 F with HF and HCI was studied by means of matrix‐isolation infrared spectroscopy. Gaseous MnO 3 F reacts with HCl forming MnO 3 Cl; some evidence for the probable existence of MnO 3 FHF complexes is also presented. Isotopic data ( 35/37 Cl) obtained from matrix‐isolation spectra unknown fundamentals (from the spectrum of the solid substance) as well as a vibrational analysis are reported for MnO 3 Cl.

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