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Interaction of MnO 3 F with HF and HCl: Matrix‐isolation infrared spectral studies. The vibrational spectrum of MnO 3 Cl
Author(s) -
Varetti E. L.,
Müller A.
Publication year - 1978
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.19784420131
Subject(s) - matrix isolation , infrared spectroscopy , infrared , matrix (chemical analysis) , chemistry , spectral line , spectroscopy , analytical chemistry (journal) , materials science , physics , organic chemistry , optics , chromatography , quantum mechanics , astronomy
Abstract The interaction MnO 3 F with HF and HCI was studied by means of matrix‐isolation infrared spectroscopy. Gaseous MnO 3 F reacts with HCl forming MnO 3 Cl; some evidence for the probable existence of MnO 3 FHF complexes is also presented. Isotopic data ( 35/37 Cl) obtained from matrix‐isolation spectra unknown fundamentals (from the spectrum of the solid substance) as well as a vibrational analysis are reported for MnO 3 Cl.