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A novel synthesis and crystal data for thallium(III) oxide bromide
Author(s) -
Günter John R.
Publication year - 1978
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.19784380121
Subject(s) - thallium , orthorhombic crystal system , bromide , bromine , oxide , chemistry , crystal structure , inorganic chemistry , crystallography , materials science , organic chemistry
Thallium(III) oxide bromide, TlOBr, has been prepared from thallium(I) carbonate and liquid bromine. It crystallizes in an orthorhombic unit cell with, a = 4.147(1) Å, b = 3.760(1) Å, c = 8,706(3) Å, Z = 2, space group Pmmn, and is isomorphous to InOBr (FeOCl type).