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Iridium(III)‐Hydride Complexes. Synthesis and characterization of para‐ and meta‐substituted benzeneseleninato derivatives
Author(s) -
Preti C.,
Tosi G.
Publication year - 1977
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.19774320136
Subject(s) - denticity , iridium , chemistry , hydride , monomer , ligand (biochemistry) , stereochemistry , characterization (materials science) , medicinal chemistry , crystallography , organic chemistry , crystal structure , materials science , metal , catalysis , nanotechnology , polymer , receptor , biochemistry
Complexes of IrH 3 (PPh 3 ) 2 with para‐ and meta‐substituted benzeneseleninic acids are reported and characterized by spectroscopic methods and molecular weight determinations. The complexes resulted of the type [IrH 2 (PPh 3 ) 2 (X–PhSeO 2 )], monomeric, with the ligand acting as bidentate seleninato‐O, Se. The possible stereochemistry of the complexes is discussed on the light of the obtained results.