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Transition Metal Chloride Chelates with 1,10‐Phenanthroline N‐Oxide
Author(s) -
Speca A. N.,
Pytlewski L. L.,
Karayannis N. M.
Publication year - 1976
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.19764220211
Subject(s) - phenanthroline , transition metal , chemistry , oxide , chelation , metal , chloride , inorganic chemistry , yield (engineering) , infrared spectroscopy , crystallography , nuclear chemistry , materials science , catalysis , organic chemistry , metallurgy
1,10‐Phenanthroline N‐oxide(L) interacts with 3d metal chlorides to yield the following chelates: [CrL 2 Cl 2 ]Cl · H 2 O; [FeL 2 Cl 2 ]Cl; [FeLCl 2 ] x (x = 1 or 2); [MnL 2 Cl 2 ]; [ClLMnCl 2 MnLCl] · 2 H 2 O; [CoL 2 Cl 2 ] · H 2 O; [CoLCl 2 ] · H 2 O; [NiL 2 Cl 2 ] · 2 H 2 O; [CuL 2 Cl]Cl · 2 H 2 O or [CuL 2 Cl 2 ] · 2 H 2 O; and [ZnL 3 ][ZnCl 4 ] · 2 H 2 O. These complexes were characterized by means of their infrared and electronic spectra, magnetic susceptibilties, X‐ray powder diffraction patterns and molar conductivities.