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Halogeno‐Bi(piperidyldiselenocarbamate) Complexes of Arsenic, Antimony, and Bismuth
Author(s) -
Manoussakis G. E.,
Tsipis C. A.,
Christophides A. G.
Publication year - 1975
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.19754170308
Subject(s) - antimony , bismuth , arsenic , halogen , chemistry , inorganic chemistry , organic chemistry , alkyl
The preparation of twelve new piperidyldyldiselenocarbamate complexes of Arsenic, Antimony, and Bismuth is described. The reaction of the tri(piperidyldiselenocarbamate) complexes of arsenic, antimony, and bismuth with halogens produces halogeno‐bi(piperidyldiselenocarbamate) complexes of the general formula XM(Pipdsc) 2 (X = Cl, Br or I and Pipdsc = (CH 2 ) 5 NCSe 2, M = As, Sb, Bi). Possible structures are discussed for these new complexes based on spectral and chemical observations. The properties and the spectroscopic data of the prepared compounds are compared to those of the corresponding dithiocarbamates.