The Thermal Decomposition of Nb 3 O 7 Cl and NbO 2 F | Zendy

Kodama H. | Zendy; Goto M. | Zendy

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The Thermal Decomposition of Nb 3 O 7 Cl and NbO 2 F

Author(s) -

Kodama H.,

Goto M.

Publication year - 1975

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.19754150212

Subject(s) - thermal decomposition , decomposition , natural bond orbital , argon , oxygen , chemistry , analytical chemistry (journal) , materials science , inorganic chemistry , computational chemistry , density functional theory , organic chemistry

The thermal decompositions of Nb 3 O 7 Cl in atmosphere of argon and oxygen were carried out and the decomposition formulae were determined as follows:The decomposition products in each atmospheres were found to be the T‐form Nb 2 O 5 and H‐form Nb 2 O 5 . It was, however, observed that if an amount of special polymorphic form of Nb 2 O 5 has been added to the starting material, Nb 3 O 7 Cl, the decomposition product came to contain a larger proportion of the seeded form. NbO 2 F was decomposed in the oxygen atmosphere. The decomposition product appeared as the P‐form Nb 2 O 5 and transformed into the N‐form Nb 2 O 5 . In the case of the thermal decomposition of NbO 2 F, no appreciable seeding effect was observed.

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