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Transition metal Complexes with Bis(2′‐quinolyl)‐2,6‐pyridine
Author(s) -
Bonomo R. P.,
Musumeci S.,
Rizzarelli E.,
Seminara A.
Publication year - 1975
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.19754140210
Subject(s) - transition metal , pyridine , acetonitrile , chemistry , imine , metal , infrared spectroscopy , elemental analysis , inorganic chemistry , ligand (biochemistry) , molar conductivity , chelation , medicinal chemistry , organic chemistry , biochemistry , receptor , catalysis
Studies on the complexes of transition metals with the tridentate imine ligand bis(2′‐quinolyl)‐2, 6‐pyridine have been carried out. On the basis of the elemental analysis data and the molar electrical conductivities, the chelates have been assigned the general formula [Me(C 23 H 15 N 3 ) 2 ](ClO 4 ) 2 , where Me was Fe(II), Co(II), Mn(II), Cu(II) and Ni(II). Their electronic spectra in the solid state and in acetonitrile solution, as well as their infrared spectra have been reported and discussed.