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R AMAN Spectra of Peroxides
Author(s) -
Eysel H. H.,
Thym S.
Publication year - 1975
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.19754110202
Subject(s) - alkaline earth metal , alkali metal , raman spectroscopy , chemistry , spectral line , inorganic chemistry , analytical chemistry (journal) , transition metal , mineralogy , environmental chemistry , physics , optics , organic chemistry , astronomy , catalysis
The R AMAN spectra of solid polycristalline samples of peroxides of alkali metals, alkaline earths, and two group II transition metals have been measured. The OO stretch vibration produces an intense band in the expected frequency region of 750 to 850 cm −1 . The observation of a weak band at 815 cm −1 indicates the existence of BeO 2 . Frequency shifts in the hydrates of alkali and alkaline earth peroxides support different water association.