Studies on kinetics and mechanism of the reaction of sulphur dioxide and nitrogen oxides with gaseous ammonia. II. Thermodynamic Equilibria in the System SO 2 , NH 3 , H 2 O, and CO 2 | Zendy

Czarnecki J. | Zendy; Haber J. | Zendy; PawlikowskaCzubak J. | Zendy; Pomianowski A. | Zendy

Premium

Studies on kinetics and mechanism of the reaction of sulphur dioxide and nitrogen oxides with gaseous ammonia. II. Thermodynamic Equilibria in the System SO 2 , NH 3 , H 2 O, and CO 2

Author(s) -

Czarnecki J.,

Haber J.,

PawlikowskaCzubak J.,

Pomianowski A.

Publication year - 1974

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.19744100214

Subject(s) - chemistry , ammonia , ammonium , sulfur dioxide , thermodynamics , kinetics , sulfur , partial pressure , nitrogen , inorganic chemistry , equilibrium constant , oxygen , organic chemistry , quantum mechanics , physics

The temperature dependence of the equilibrium constant of the formation of ammonium sulphite from SO 2 , NH 3 , and H 2 O given by theoretical equation derived by Wolfkowitsch and Zirlin has been confirmed by calculations based on the accessible experimental data. Substitution of SO 2 by CO 2 in solid ammonium sulphite can take place when partial pressure of CO 2 exceeds at least 10 4 times that of SO 2 .

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research