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The Catalytic Oxidation of Hydrogen on Nickel Oxides
Author(s) -
McC. Jamieson D.,
Klissurski D. G.,
Ross R. A.
Publication year - 1974
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.19744090113
Subject(s) - catalysis , activation energy , nickel , carbon monoxide , chemistry , hydrogen , oxide , inorganic chemistry , oxygen , redox , organic chemistry
The catalytic oxidation of hydrogen on highly‐dispersed and sintered nickel oxides has been studied by a static method and the existence of two different kinetic rcgions established. Between 0 and 100°C the initial catalytic activity was not ionary and a strong poisoning effect of the reaction product was observed at all temperatnres up to 250°C. The activation energy of the reaction based on the initial reaction rates on freshly‐ outgassed oxide surfaces had a low value of 1–2 kcal. mole −1 with both preparations. Between 250 and 350°C stationary catalytic activity was observed and the activation energy of the reaction was significantly higher, 12–14 kcal . mole −1 . The change of the activation energy is discussed in terms of the participation in the reaction of oxygen species in the catalyst surface layer which have different reactivities in the two temperature regions. A close analogy is noted between the carbon monoxide and hydrogen oxidation reactions on nickel oxide and a compensation effect is illustrated for a series of oxidation reactions on the oxide.