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Preparation and Characterisation of a New Thallium(I) Uranate(VI), Tl 4 UO 5
Author(s) -
Giridharan A. S.,
Udupa M. R.,
Aravamudan G.
Publication year - 1974
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.19744070310
Subject(s) - thallium , volatilisation , oxide , chemistry , inorganic chemistry , nuclear chemistry , radiochemistry , organic chemistry
A new thallium(I) uranate(VI) of composition Tl 4 UO 5 was isolated and characterised by X‐ray, i. r. and chemical analyses. The compound dissociated into thallium(I) oxide and Tl 2 UO 4 on heating to 230°C and its subsequent thermal behaviour depended on the volatilisation and oxidation characteristics of the thallium(I) oxide released.