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Core electron binding energies of thiazyl fluoride and other sulfur compounds
Author(s) -
Jolly W. L.,
Lazarus M. S.,
Glemser O.
Publication year - 1974
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.19744060212
Subject(s) - sulfur , chemistry , valence (chemistry) , atomic orbital , binding energy , fluorine , core electron , core (optical fiber) , atomic physics , covalent bond , crystallography , electron , computational chemistry , materials science , organic chemistry , physics , quantum mechanics , composite material
Core electron binding energies were measured for the atoms in NSF 3 , SF 5 Cl, and S 2 Cl 2 . These data and similar data from the literature for other sulfur compounds were correlated by the point charge potential method using CHELEQ atomic charges. The results indicate that the bonding in a wide variety of sulfur compounds can be explained using only s and p valence orbitals. The low fluorine 1s bonding energies observed for NSF 3 and OSF 2 are attributed to “no‐bond” resonance structures.