Octahedral cobalt (III) complexes of the chloropentammine type. XXXII. Cis‐[Coen 2  (n‐C x H 2x+1 NH 2 )Cl] 2+  Complexes Containing Long Paraffinic Chains | Zendy

Chan S. C. | Zendy; Lee C. K. | Zendy

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Octahedral cobalt (III) complexes of the chloropentammine type. XXXII. Cis‐[Coen 2 (n‐C x H 2x+1 NH 2 )Cl] 2+ Complexes Containing Long Paraffinic Chains

Author(s) -

Chan S. C.,

Lee C. K.

Publication year - 1974

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.19744040108

Subject(s) - octahedron , cobalt , solvolysis , chemistry , crystallography , infrared spectroscopy , reaction rate constant , kinetic energy , infrared , analytical chemistry (journal) , inorganic chemistry , crystal structure , kinetics , physics , hydrolysis , biochemistry , organic chemistry , optics , chromatography , quantum mechanics

Salts of the cis‐[Coen 2 (n‐C x H 2x+1 NH 2 )Cl] 2+ cations where x = 4–12 have been prepared, and their visible and infrared spectra measured. Rate constants for their solvolysis have been determined over a range of temperatures and activation parameters calculated. These spectral and kinetic data are briefly discussed.

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