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Reaction of nitric oxide with tetravalent rhenium compounds
Author(s) -
Rakshit S.,
Sen B. K.,
Bandyopadhyay P.
Publication year - 1973
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.19734010213
Subject(s) - rhenium , chemistry , halide , aqueous suspension , aqueous solution , stoichiometry , suspension (topology) , nitric acid , inorganic chemistry , oxide , nitric oxide , nuclear chemistry , organic chemistry , homotopy , mathematics , pure mathematics
Nitric oxide reacts with hydrated ReO 2 in aqueous suspension at 70–80°C to produce quantitatively Re(NO)(OH) 3 , ReO 4 −and NH 4 + . [Re(NO)Cl 5 ] 2− and ReO 4 −are produced in stoichiometric quantities by the reaction of either NO with ReO 2 suspension in 6 N HCl or by the action of a mixture of NO and HCl with an aqueous ethanolic or aqueous suspension of ReO 2 at 70–80°C. Passage of NO over 1,10‐phenanthrolinium hexahalorhenate(IV) at 220°C produces nitrosyl halide, hydrogen halide and [Re(NO) (phen)Cl 3 ] or [Re(NO)(phen)Br 3 ].
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