Enthalpies of mixing of charge unsymmetrical binary fused salt systems: ZnX 2 AX (A = Li, Cs, Ag; X = Cl, Br) | Zendy

Papatheodorou G. N. | Zendy; Kleppa O. J. | Zendy

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Enthalpies of mixing of charge unsymmetrical binary fused salt systems: ZnX 2 AX (A = Li, Cs, Ag; X = Cl, Br)

Author(s) -

Papatheodorou G. N.,

Kleppa O. J.

Publication year - 1973

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.19734010203

Subject(s) - chemistry , mixing (physics) , alkali metal , inorganic chemistry , salt (chemistry) , chloride , binary system , metal , binary number , analytical chemistry (journal) , organic chemistry , physics , arithmetic , mathematics , quantum mechanics

The enthalpies of mixing (ΔH M ) of the following binary fused‐salt mixtures have been determined calorimetrically: ZnCl 2 CsCl, ZnCl 2 LiCl, ZnCl 2 AgCl, ZnBr 2 CsBr, ZnBr 2 LiBr at 665°C; ZnCl 2 CsCl, ZnCl 2 AgCl, and ZnCl 2 ZnBr 2 at 495°C. The results are discussed with respect to the following points: (1) Comparison with the transition metal chloride‐alkali chloride systems, (2) “complexing” in the mixture. (3) effect of the network‐like structure of pure ZnX 2 , and (4) effect of temperature.

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