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Thorium Tetra‐Chloride and Uranyl Sulphate Complexes with Phenyl Hydrazine and Benzidine
Author(s) -
Rahman S. M. F.,
Ahmad Jamil,
Haq M. Mazharul
Publication year - 1972
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.19723920316
Subject(s) - chemistry , tetrahydrofuran , benzidine , hydrazine (antidepressant) , uranyl , dimethylformamide , chloride , thorium , tetra , inorganic chemistry , molar ratio , medicinal chemistry , nuclear chemistry , organic chemistry , uranium , catalysis , ion , materials science , chromatography , solvent , metallurgy
Phenyl hydrazine (Ph) and benzidine (B) form complexes with thorium tetrachloride and uranyl sulphate of the general composition correspond to: [ThPh 4 ]Cl 4 , [ThB 2 Cl 2 ]Cl 2 , [UO 2 Ph]SO 4 and [UO 2 B(THF)]SO 4 (THF = tetrahydrofuran). The compounds were isolated, analysed and their molar conductivities were determined in dimethyl sulphoxide and dimethylformamide. The nature of coordination was discussed in the light of i.r. spectral assignments.