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Gold Diselenocarbamato Complexes
Author(s) -
van der Linden J. G. M.,
Nijssen W. P. M.
Publication year - 1972
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.19723920113
Subject(s) - chemistry , crystallography , sulfur , electrical resistivity and conductivity , conductivity , physics , organic chemistry , quantum mechanics
The preparation, u. v. and i. r. spectra and electrical conductivity of some gold diselenocarbamato complexes Au(et 2 dsc), [Au(et 2 dsc) 2 ]Br, [Au(bu 2 dsc) 2 ] [AuBr 2 ] and Br 2 Au(et 2 dsc) are reported. [Au(et 2 dsc) 2 ]Br undergoes a reversible one‐electron reduction with E 1/2 = — 0.43 V vs. SCE, in contrast with the irreversible reduction observed for the analogous sulfur complex.