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Preparation of some nickel(II) and copper(II) complexes of the S CHIFF ‐Base derived from Acetophenone and Ethylenediamine
Author(s) -
Dey K.,
De R. L.,
Sen S. K.,
Chatterjee K. K.
Publication year - 1972
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.19723890213
Subject(s) - chemistry , acetophenone , acetylacetone , ethylenediamine , schiff base , copper , denticity , nickel , chelation , ligand (biochemistry) , inorganic chemistry , polymer chemistry , crystallography , crystal structure , organic chemistry , catalysis , biochemistry , receptor
Abstract Preparation and properties of the following Ni II and Cu II complexes of the Schiff base derived from acetophenone and ethylenediamine (BAPE) and also of the mixed Ni II and Cu II chelates with BAPE and acetylacetone (acac‐H) are described:In each case the Schiff base, BAPE, acts as a neutral bidentate ligand. The complexes are characterised by electronic spectra, magnetic susceptibilities, conductivities and elemental analyses. Pseudotetrahedral structure is proposed for M(BAPE)C1 2 , while tetragonal structure for [M(BAPE)(acac)(H 2 O) 2 ]C l O 4 (M = Ni and Cu). The complex [Ni(BAPE) (acac)]ClO 4 has been found to be square planar.