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Thermal study on some Nitrosyl Complexes of Rhenium
Author(s) -
Hait D. K.,
Sen B. K.,
Bandyopadhyay P.
Publication year - 1972
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.19723880213
Subject(s) - rhenium , pyridine , thermal decomposition , decomposition , chemistry , phenanthroline , medicinal chemistry , inorganic chemistry , organic chemistry
Study of the thermal decomposition of (MH) 2 [ReCl 5 (NO)] where M stands for pyridine, 2,2′ dipyridyl and 1,10 phenanthroline in carbon dioxide atmosphere is described. Pyridine compound produces pyH[ReCl 4 py(NO)] at 250°C and [ReCl 3 py 2 (NO)] at 400°C. Dipyridyl and phenanthroline compounds produce [ReCl 3 (dipy)(NO)] and [ReCl 3 (phen)(NO)] at 210°C and 220°C respectively. The acid H[ReCl 4 py(NO)] decomposes under similar condition at 200°C to produce [ReCl 3 (NO)] and [ReCl 3 py 2 (NO)] in equivalent quantities.