Thermal study on some Nitrosyl Complexes of Rhenium | Zendy

Hait D. K. | Zendy; Sen B. K. | Zendy; Bandyopadhyay P. | Zendy

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Thermal study on some Nitrosyl Complexes of Rhenium

Author(s) -

Hait D. K.,

Sen B. K.,

Bandyopadhyay P.

Publication year - 1972

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.19723880213

Subject(s) - rhenium , pyridine , thermal decomposition , decomposition , chemistry , phenanthroline , medicinal chemistry , inorganic chemistry , organic chemistry

Study of the thermal decomposition of (MH) 2 [ReCl 5 (NO)] where M stands for pyridine, 2,2′ dipyridyl and 1,10 phenanthroline in carbon dioxide atmosphere is described. Pyridine compound produces pyH[ReCl 4 py(NO)] at 250°C and [ReCl 3 py 2 (NO)] at 400°C. Dipyridyl and phenanthroline compounds produce [ReCl 3 (dipy)(NO)] and [ReCl 3 (phen)(NO)] at 210°C and 220°C respectively. The acid H[ReCl 4 py(NO)] decomposes under similar condition at 200°C to produce [ReCl 3 (NO)] and [ReCl 3 py 2 (NO)] in equivalent quantities.

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