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Physicochemical studies on Iron(III)‐atrolactate and Iron(III)‐α‐hydroxyisobutyrate chelates
Author(s) -
Gupta Kalyan K. Sen,
Chatterjee A. K.
Publication year - 1971
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.19713840313
Subject(s) - chemistry , chelation , medicinal chemistry , stereochemistry , inorganic chemistry
Atrolactic as well as α‐hydroxyisobutyric acids form yellow 1:1‐ complexes with iron(III) which could be isolated. The nature of the complexes has been studied spec‐trophotometrically. The equilibrium constants as well as the thermodynamic parameters, e.g. – ΔG, ΔH, ΔS, of the complexes have been evaluated.