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Schiff base derivatives of titanium(IV) and zirconium(IV)
Author(s) -
Prashar P.,
Tandon J. P.
Publication year - 1971
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.19713830110
Subject(s) - zirconium , bifunctional , schiff base , titanium , chemistry , base (topology) , ion , inorganic chemistry , polymer chemistry , medicinal chemistry , organic chemistry , mathematics , catalysis , mathematical analysis
The reactions of a few bifunctional and tridentate Schiff bases with titanium‐(IV) and zirconium(IV) isopropoxides in equimolar and bimolar ratios are described. The resulting compounds have been obtained in almost quantitative yields and are of the general formulae M(SB) x (OPr i ) 4−2X (where M = Ti or Zr; SB‐ = anion of the Schiff base SBH 2 and x = 1 or 2). Their molecular weights have been determined ebullioscopically and IR spectra recorded.