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New complexes of gold(III) with pseudohalides. II. The synthesis of linkage isomers of the Dicyanodithiocyanatoaurate(III) Complex Ion
Author(s) -
Negoiu D.,
Båloiu L. M.
Publication year - 1971
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.19713820113
Subject(s) - linkage isomerism , cyanide , chemistry , linkage (software) , tetraethylammonium , potassium , ion , stereochemistry , inorganic chemistry , organic chemistry , metal , biochemistry , gene
Abstract The synthesis of the linkage isomers of the dicyanodithiocyanatoaurate(III) complex ion, as potassium and tetraethylammonium salts, is presented. The structure of the two isomers is established by IR spectra. The existence of the isomers is explained by the influence of the two cyanide groups from the inner coordination sphere.