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Nuclear Magnetic Resonance and Electronic Spectral Study of oxalato‐ammine cobalt(III)complexes
Author(s) -
Biradar N. S.,
Pujar M. A.
Publication year - 1970
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.19703790116
Subject(s) - cobalt , nuclear magnetic resonance , crystal (programming language) , series (stratigraphy) , chemistry , crystal field theory , spectral line , resonance (particle physics) , crystallography , materials science , inorganic chemistry , physics , atomic physics , ion , organic chemistry , astronomy , paleontology , computer science , biology , programming language
A series of oxalato‐ammine cobalt(III) complexes were prepared. The nuclear magnetic resonance spectral properties of this series have been measured. The chemical shifts observed in these complexes have been explained on the basis of the theory of G RIFFITH and O RGEL . The splitting of the bands have been examined. The various crystal field parameters Dq′, B, Dt′ have been discussed.