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Studies on some N‐Acyl N‐phenylhydroxylamines as metal‐complexing lingands. IV. Determination of Formation constants of U(VI) chelates
Author(s) -
Ghosh N. N.,
Siddhanta G.
Publication year - 1970
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.19703750209
Subject(s) - uranyl , chemistry , chelation , metal , aqueous solution , ionic strength , inorganic chemistry , acetone , ionic bonding , stability constants of complexes , medicinal chemistry , organic chemistry , ion
The formation of uranyl complexes of N‐acetyl, ‐chloroacetyl, ‐benzoyl and ‐o, ‐m and ‐p nitrobenzoyl N‐phenylhydroxylamines have been studied potentiometrically in 1:1 aqueous acetone at constant ionic strenght (m̈ = 0.5). Only the first step could be followed and the final results have been evaluated by projection strip method. The stabilities follow a general order.