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Addition compounds of thionyl halides with tertiary amines
Author(s) -
Paul R. C.,
Khurana H.,
Vasisht S. K.,
Chadha S. L.
Publication year - 1969
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.19693700310
Subject(s) - thionyl chloride , chemistry , halide , isoquinoline , pyridine , quinoline , piperidine , bromide , nitrogen atom , medicinal chemistry , photochemistry , organic chemistry , polymer chemistry , inorganic chemistry , chloride , ring (chemistry)
Thionyl chloride and bromide react with pyridine, β‐ and γ‐picoline, quinoline, isoquinoline and piperidine giving rise to addition compounds having 1:2 stoichiometry (thionyl halide: base). Infrared spectral data regarding the complexes formed indicate the coordination of the base molecule through its nitrogen atom to the sulphur atom of thionyl halide.