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Mercury(II) oxide as a ligand. II. Addition Compounds of the Transition Metal Selenates
Author(s) -
Pothoff G. F.,
Balt S.
Publication year - 1968
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.19683620313
Subject(s) - selenate , mercury (programming language) , chemistry , oxide , metal , transition metal , inorganic chemistry , metal ions in aqueous solution , octahedron , selenium , coordination complex , ion , ligand (biochemistry) , nuclear chemistry , organic chemistry , biochemistry , receptor , computer science , programming language , catalysis
Abstract A study of the visible and infrared spectra and the magnetic moments of the addition compounds of mercury(II) oxide with some M II transition metal selenates has revealed that the metal ions in these compounds have nearly octahedral environment. M II ‐coordination to the selenate ion has only been found in compounds with a HgO content below that of the basic selenate HgSeO 4 · 2 HgO. Mercury oxide in its ligand field behaviour was found to resemble water closely.