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Some intermediates in the Reaction between Vanadium(IV) and Vanadium(V)
Author(s) -
Sarma P. L.,
Davis M. S.
Publication year - 1967
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.19673530513
Subject(s) - vanadium , chemistry , sulfate , inorganic chemistry , ammonium metavanadate , organic chemistry
Vanadium(IV) and vanadium(V) react in acid media forming green intermediates whose compositions depend upon the concentrations of the reactants, pH of the media, and time of reaction. Two solid intermediates separated from mixtures of vanadyl sulfate and sodium metavanadate solutions more than a year ago appear stable at room temperature even to this date.