Premium
Conductometric, cryoscopic and infrared Studies on Rare Earth Perchlorates
Author(s) -
Krishnamurthy V. N.,
Soundararajan S.
Publication year - 1967
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.19673490315
Subject(s) - perchlorate , infrared , chemistry , infrared spectroscopy , rare earth , conductance , ion , analytical chemistry (journal) , inorganic chemistry , molecule , mineralogy , environmental chemistry , condensed matter physics , organic chemistry , optics , physics
Perchlorates of La, Ce, Pr, Nd, Sm, Gd, and Y have been prepared and their conductance, cryoscopic and infrared studies indicate the non‐coordinating tendency of the perchlorate ion. The observed splitting of the v 3 band in the IR spectra is due to a non‐uniform field arising from the water molecules around the cation.