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Electric Moments of some Addition Compounds of Antimony Pentachloride
Author(s) -
Jain S. R.,
Soundararajan S.
Publication year - 1965
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.19653370315
Subject(s) - benzene , antimony , dipole , chemistry , ligand (biochemistry) , polarity (international relations) , inorganic chemistry , oxygen , computational chemistry , photochemistry , organic chemistry , receptor , biochemistry , cell
The dipole moments of the addition compounds of antimony pentachloride with organic ligands containing different functional groups have been measured in benzene solution at 35°C. The moments of the 1:1 complexes depend directly on the polarity of the ligand containing oxygen as the donor atom. Complexes having SbCl 5 :ligand ratio of 1:2 are found to be dissociated in solution.