Physico‐chemical studies on the Titanium(III)‐Chloride‐2‐2′‐dipyridyl Complex | Zendy

Tariq Siddiqui M. | Zendy; Ahmad Naseer | Zendy; Rahman S. M. F. | Zendy

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Physico‐chemical studies on the Titanium(III)‐Chloride‐2‐2′‐dipyridyl Complex

Author(s) -

Tariq Siddiqui M.,

Ahmad Naseer,

Rahman S. M. F.

Publication year - 1965

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.19653360116

Subject(s) - potentiometric titration , chloride , titanium , conductometry , chemistry , titration , inorganic chemistry , complex formation , yield (engineering) , molar ratio , ion , nuclear chemistry , materials science , organic chemistry , metallurgy , catalysis

Titanium(III) chloride was found to undergo complex formation with 2.2′‐dipyridyl producing a white crystalline compound. The composition of the complex in solution was found to be in the molar ratio of 1:2 (titanium:dipyridyl) by conductometric and potentiometric titrations. The complex was also recrystallised, and its analysis confirmed the results of the titrations. The complex was found to yield a single free chloride ion in solution. A possible structure of the complex is proposed.

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