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Physico‐chemical studies on the Titanium(III)‐Chloride‐2‐2′‐dipyridyl Complex
Author(s) -
Tariq Siddiqui M.,
Ahmad Naseer,
Rahman S. M. F.
Publication year - 1965
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.19653360116
Subject(s) - potentiometric titration , chloride , titanium , conductometry , chemistry , titration , inorganic chemistry , complex formation , yield (engineering) , molar ratio , ion , nuclear chemistry , materials science , organic chemistry , metallurgy , catalysis
Titanium(III) chloride was found to undergo complex formation with 2.2′‐dipyridyl producing a white crystalline compound. The composition of the complex in solution was found to be in the molar ratio of 1:2 (titanium:dipyridyl) by conductometric and potentiometric titrations. The complex was also recrystallised, and its analysis confirmed the results of the titrations. The complex was found to yield a single free chloride ion in solution. A possible structure of the complex is proposed.