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Some Reactions of N‐Bromobistrifluoromethylamine
Author(s) -
Emeléus H. J.,
Tattershall B. W.
Publication year - 1964
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.19643270308
Subject(s) - yield (engineering) , chemistry , medicinal chemistry , materials science , metallurgy
N‐Bromobistrifluoromethylamine, (CF 3 ) 2 NBr reacts with NO 2 , NO and CO to yield (CF 3 ) 2 NONO, (CF 3 ) 2 NNO and (CF 3 ) 2 NCOBr, respectively. The reaction of (CF 3 ) 2 NBr with unsaturated hydrocarbons and fluorocarbons has been confirmed, reaction with C 2 H 4 C 2 H 2 and C 2 F 4 giving (CF 3 ) 2 NC 2 H 4 Br, (CF 3 ) 2 NC 2 H 2 Br and (CF 3 ) 2 NC 2 F 4 Br. Reaction with AgCN yields CF 3 N CF 2 , and that with Ag 2 CO 3 , CF 3 N NCF 3 , as the chief product.