Investigations on Cyano Complexes. II. Cyano Mercurate(II)‐complexes | Zendy

Azzam A. M. | Zendy; Shimi I. A. W. | Zendy

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Investigations on Cyano Complexes. II. Cyano Mercurate(II)‐complexes

Author(s) -

Azzam A. M.,

Shimi I. A. W.

Publication year - 1964

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.19643270112

Subject(s) - potentiometric titration , chemistry , stability constants of complexes , titration , electrode , inorganic chemistry , electrochemistry , aqueous solution

By potentiometric titrations, in addition to the complexes known in literature, the anions [Hg(CN) 5 ] 3− and [Hg(CN) 6 ] 4− have been evaluated in concentrated solutions of KCN. Instability constants together with standard potentials and free energies were calculated.—After the complete formation of Hg(CN) 2 and addition of slight excess of HgCl 2 the electrode became incapacitated on account of the formation of Hg 2 Cl 2 .

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